Genesis of Iron Ore Caves in the Iron Quadrangle, Minas Gerais, Brazil Ceth W. Parker 1, Julie A. Wolf 2, Augusto S. Auler 3, Hazel A. Barton 1,2 and John M. Senko 1,2,* ... (III) (predominantly hematite) associated with banded iron formation (BIF), iron ore, and mine spoil. In all cases, the addition of a humic acid analogue enhanced Fe(III)Web