Nanostructured germanium synthesized by high-pressure

However, the very small pore sizes (< 10 nm) of many mesoporous silicas make traditional deposition methods for germanium difficult, resulting in aggregated …Web

Electrochemical Behavior of Reduced Graphene Oxide Supported Germanium

An attempt to control the particle size of germanium nitride was made by adjusting the ratio between the loading of germanium dioxide and graphene oxide. Decreasing of GeO 2 loading to 20 wt.% (GeO 2-rGO-20) resulted in a uniform coating of Ge 3 N 4 crystalline phase, ... The small shoulder, at 0.2 V, on the first discharging scan …Web

Frontiers | Optical properties of germanium nanoparticles …

Where "q" is expressed in terms of 2π /a, and a is the lattice constant of Ge (0.5658 nm), d is the size of the Ge nanoparticle. Γ 0 (= 3.2 cm −1) is the natural line width of the transverse optical (TO) phonon in crystalline bulk Ge at room temperature and ω(q) is the TO phonon dispersion frequency relation at q.By using the above equation along with …Web

In Situ Focused Ion Beam-Scanning Electron Microscope …

germanium particles cycled at different current rates. Figure 1a−d shows the voltage profiles of particles cycled at 0.12, 0.3, 1, and 3 nA (about 0.1, 0.21, 0.8, and 7.5 C rate), respectively. ... For the particle cycled at 0.3 nA, one small crack appears on the surface after lithiation (indicated by the arrow in Figure 1j). At the end of ...Web

New horizons for the synthesis of nanoparticles: …

The here described method for the mild synthesis of germanium nanoparticles is based on the metastable character of Ge (I)Br solutions (solvent: mixture of toluene or THF and P n Bu 3 as a donor component) …Web

Particle dark matter and solar axion searches with a small germanium

A small (234 g) germanium detector of natural isotopic abundance, with an energy threshold of 2.5 keV and an energy resolution of 430 eV at the 10.37 keV X-ray 68 Ga peak, has collected data up to a statistics of 311 days, in a search for WIMPs. The timing information of the same set of data has allowed also a search for the characteristic time ...Web

Extraction of Germanium from Low-Grade Germanium-Bearing …

Moreover, germanium presented a close relationship with As, Pb and S, as shown in Figure 2 c. Spot 1 represented a C-rich particle containing low contents of S. Spot 2 was viewed as silicon dioxide owing to high contents of Si and O. Moreover, Spot 3 was recognized as calcium sulfate because of high contents of Ca, S and O.Web

High pressure acid leaching of low germanium bearing silica …

The large-volume long-chain polymer SiO 2 gradually depolymerized into small-volume oligomeric SiO 2 monomers as the leaching temperature increased, converting the flocculent particles of polysilicic acid to low activity hydrated SiO 2. This resulted the reduction of adsorption performance causing the higher leaching efficiency …Web

Anomalous surface structure of fine germanium particles

Clean surfaces of germanium particles with diameters of 2–10 nm are studied by ultrahigh-vacuum high-resolution electron microscopy. The surfaces are found to be reconstructed in the profile images: on the (001) facet the asymmetric dimer structure is formed, while on the (111) facet an island of a finite size with a specific reconstruction is …Web

Photoluminescent polysaccharide-coated germanium(IV) oxide

A small-angle X-ray scattering study of TEOG hydrolysis in water demonstrated that (Ge–O) x oligomers were formed at all of the studied mole fractions of germanium. However, their crystallization into GeO 2 particles only occurred when the molar concentration of germanium exceeded its solubility [ 24 ].Web

Light Emission from Germanium Nanostructures | SpringerLink

Abstract. This Chapter discusses the phenomena associated with germanium (Ge) nanocrystals emitting near infrared radiation under optical excitation. We describe how the emission properties are influenced by various effects, including those of strain and particle confinement, as well as excitation mechanisms. Two example systems are …Web

Germanium in Lithium-Ion and Sodium-Ion Batteries (A Review)

A pod-like Ge‒C composite in which spherical germanium particles filled the inner space of nanotube of carbon doped with nitrogen was described in work . A capacity of 900 mА h/g at the 8 С rate was realized with this material. Germanium–graphene composites were first mentioned in 2012 [243, 244, 257]. The results of the first works did ...Web

New horizons for the synthesis of nanoparticles: Germanium

access to small germanium nanoparticles within the size range up to 100 Å (Figure S3a,b in Supplementary ... from a reaction of the particles with a small amount of water or oxygen during the ...Web

Particle dark matter and solar axion searches with a small …

A small (234 g) germanium detector of natural isotopic abundance, with an energy threshold of 2.5 keV and an energy resolution of 430 eV at the 10.37 keV X-ray …Web

Chemistry of Germanium (Z=32)

Chemical Properties. At a temperature of 250 °C, germanium slowly oxidizes to G e O 2. Germanium dissolves slowly in concentrated sulfuric acid, and is insoluble in diluted acids and alkalis. It will react violently with molten alkalis to produce [GeO 3] 2-. The common oxidation states of germanium are +4 and +2.Web

Modulating the trapping and manipulation of semiconductor particles

The small trap stiffness values measured for the germanium particles are possibly related to the generation of charge carriers in the semiconducting material as a result of laser light absorption [6]. In fact, such a phenomenon would increase the conducting character of the beads, therefore difficulting their stable trapping.Web

Study sets the first germanium-based constraints on dark …

"The energy deposited in our detector following a dark matter particle interaction is expected to be extremely small ( Citation: Study sets the first germanium-based …Web

New horizons for the synthesis of nanoparticles: Germanium

The disproportionation reaction especially gives access to small germanium nanoparticles within the size range up to 100 Å (Figure S3a,b in Supplementary material). ... 1988) underlining the sensitivity of the particles to moisture and air as the GeO 2 may result from a reaction of the particles with a small amount of water or oxygen during ...Web

Size and porosity effects on thermal conductivity of nanoporous

Emphasis is put on the influence on the effective thermal conductivity of pSi/Ge composite of several parameters, as the particle size, pore size, porosity and particle volume fraction. The limiting cases are those of zero porosity (which corresponds to bulk Si nanoparticles in Ge) and porosity tending to one (i.e. porous germanium).Web

Germanium Compounds

These tiny particles are mainly lead and contain a certain amount of zinc, sulfur, and germanium. The PbO (or Pb) on the particle surface converts into PbSO 4, and the shielding interface formed cuts off reactions between sulfuric acid and substances in the particles, preventing the leaching of zinc and germanium.Web

CHAPTER 9 RADIOACTIVE MATERIALS, …

stable helium-3 atom by emission of a weak beta particle. With the proper catalyst i.e., fire,tritium combines spontaneously with oxygen in the air and will also replace ordinary hydrogen in water or other hydrogenous material (grease or oil), causing these materials to become radioactive. c. Hazards and Health Considerations:TritiumWeb

Germanium

Created by video journalist Brady Haran working with chemists at The University of Nottingham. Explore all elements. Element Germanium (Ge), Group 14, Atomic Number 32, p-block, Mass 72.630. Sources, facts, uses, scarcity (SRI), podcasts, alchemical …Web

Synthesis of Germanium Nanospheres as High-Precision Optical …

Since trapping forces scale with the particle volume, piconewton-force measurements so far required micron-sized probes practically limiting the spatiotemporal …Web

Nano germanium incorporated thin graphite nanoplatelets: A …

Germanium nanoparticles Thin graphite Ball milling Lithium-ion batteries 1. Introduction Recently, silicon (Si), germanium (Ge) and tin (Sn) are recognised as high …Web

(PDF) Spatial distribution of gas-phase synthesized germanium

Emission of the hot particles and extinction against a continuous background were recorded by a spectrometer in the 380–703 nm and 230–556 nm ranges, respectively, selected based on the ...Web

Germanium Sub-Microspheres Synthesized by Picosecond Pulsed …

In order to corroborate our hypothesis that small educts could evolve into bigger SMSs during laser irradiation, we first synthesized Ge particles by LAL in water (10–100 nm, peak at 80 nm).Web

(PDF) Nanometer-sized colloidal germanium particles: …

[25] We investigated an amorphous germanium powder prepared from GeCI, fects for germanium particles in the size range investigated and lithium naphthalide by thermoanalysis and X-ray diffraction and or. it …Web

Light emission from germanium nanoparticles formed by ultraviolet

It is proposed that stress effects associated with the oxidation of small spherical particles allow the formed nanocrystalline Ge to survive during prolonged ultraviolet oxidation of the SiGe ...Web

Germanium Sub-Microspheres Synthesized by …

37 Citations Metrics Abstract Pulsed laser melting in liquid (PLML) has emerged as a facile approach to synthesize submicron spheres (SMSs) for various applications. Typically lasers with long...Web

High Purity Germanium: From Gamma-Ray Detection to …

Above 1 keV of initial particle energy, germanium is a good choice for the detec-tion of photon or ionizing particles. See Table 1 and Refs. [4–10] for studies, both ... quality crystals (despite being small) may be fabricated in University labs [11, 14] which show that nowadays the availability of such crystals is better thanWeb

The States and Properties of Germanium in Sulfuric Acid Solution …

With the increase of the germanium concentration from 50 mg/L to 1 g/L in a sulfuric acid solution, the size of H 2 GeO 3 colloidal particles increased from 3.59 nm to 200 nm, and the zeta potential decreased from −1.57 mV to −8.98 mV, indicating that the dispersion of H 2 GeO 3 colloidal particles was more stable with the increase of ...Web

IJMS | Free Full-Text | Stabilization of Colloidal Germanium

Germanium nanoparticles have been known and applied for a few decades in the form of colloidal solutions, ... the sensitivity of the halide-terminated particles to moisture and air as the GeO 2 results from a reaction of the particles with a small amount of water or oxygen during the measurement . The substitution of the halide atoms of the ...Web

Germanium | Encyclopedia

Radioactive isotopes are produced when very small particles are fired at atoms. These particles stick in the atoms and make them radioactive. None of the radioactive isotopes of germanium has any important commercial use. Extraction. Germanium in zinc ores is heated in the presence of chlorine gas. Germanium chloride …Web

Atomic Radius | Periodic Table of Elements

Atomic Radius in the Periodic Table of Elements. The atomic radius of a chemical element is a measure of the size of its atom, usually, the distance from the center of the nucleus to the outermost isolated electron. Because an atom does not have a discrete boundary, there are various non-equivalent definitions of atomic radius, such as Van der ...Web

How Nanowires Grow | Science

Many controversies boil down to which of two distinctly different explanations, models, or options is the correct one. On page 729 of this issue, Kodambaka et al. (1) address a long-standing controversy—whether, below a certain temperature, the growth of semiconductor nanowires involves a liquid droplet or a solid particle of the catalytic …Web

Germanium (Ge) [32] — Chemical Element — Periodic Table

Obtained from refining copper, zinc and lead. Widely used in semiconductors. It is a good semiconductor when combined with tiny amounts of phosphorus, arsenic, gallium, and antimony. Get the facts about element Germanium (Ge) [32] from the periodic table. Find physical data, electron configuration, chemical properties, aggregation states ...Web

Study sets the first germanium-based constraints on dark matter

As the energy deposits that should theoretically arise from sub-MeV dark matter particles are incredibly small (i.e., in the eV-scale), however, the associated …Web

Novel Germanium/Polypyrrole Composite for High …

The nano-sized morphology of the particles also plays a significant role, with the utilization of small particles being enhanced by their larger surface area and shorter diffusion length for the ...Web